Electrochemical Oxidation and Sensing of Methylamine Gas in Room Temperature Ionic Liquids
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چکیده
منابع مشابه
Electrochemical studies of hydrogen chloride gas in several room temperature ionic liquids: mechanism and sensing.
The electrochemical behaviour of highly toxic hydrogen chloride (HCl) gas has been investigated in six room temperature ionic liquids (RTILs) containing imidazolium/pyrrolidinium cations and range of anions on a Pt microelectrode using cyclic voltammetry (CV). HCl gas exists in a dissociated form of H(+) and [HCl2](-) in RTILs. A peak corresponding to the oxidation of [HCl2](-) was observed, re...
متن کاملElectrochemical Applications of Room - Temperature Ionic Liquids
R3 R2 There is good evidence that the first room-temperature ionic liquid or RTIL was identified and characterized by Walden in 1914, who examined the electrical conductivity of ethylammonium nitrate.1 Thus, it would not be an exaggeration to say that the very beginnings of electrochemistry involved room-temperature ionic liquids! Although once considered to be a curious subset of the general c...
متن کاملRoom Temperature Ionic Liquids
The initial objective of this project was to carry out a fundamental study of the transport characteristics of a variety of gases and organic solutes in room temperature ionic liquids. The goal was to combine information collected from a number of different experimental measurements in order to develop a fundamental understanding of the interactions governing transport in ionic liquids. Measure...
متن کاملComputational Study of Electrochemical Windows of Room-Temperature Ionic Liquids
Yong-Hui Tian, T-1; George S. Goff, Wolfgang H. Runde, C-IIAC; Enrique R. Batista, T-1 Room-temperature ionic liquids (RTIL) are regarded as green solvents due to their low volatility, low flammability, and thermal stability. RTILs exhibit wide electrochemical windows, and they show potential as media for a variety of electroplating processes. Therefore, understanding the factors dominating the...
متن کاملDynamic Heterogeneity in Room-Temperature Ionic Liquids
Room temperature ionic liquids (RTILs) are comprised of bulky organic cations and anions (Holbrey & Seddon, 1999; Weingärtner, 2008). Because of the intricate interplay of various interand intramolecular interactions, RTILs have rich dynamical properties and have found diverse applications. In particular, negligible vapor pressure of RTILs makes them a green alternative of conventional organic ...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry C
سال: 2014
ISSN: 1932-7447,1932-7455
DOI: 10.1021/jp5061045